I don’t know when the next intended quality session in suggestion / question why not PM/AM, but its 36 hours easy / recovery if you go into another PM/AM cycle the next PM (unless my maths is incorrect)
I did the PM / AM quality session thing Monday PM and Tuesday AM with PM being easy/recovery, I won’t do another quality session until Thursday though. Tomorrow evening might progress easy to moderate if recovering well.
Summary
Friday - Rest / off
Saturday - AM Hard, in the form of moderate volume (25km)
Sunday - AM Easy bike, PM Very easy run, technical swim i.e easy
Monday - AM Recovery bike, PM Quality run 17km including 12km MP to tempo
Tuesday - AM Quality Bike 2x 20’ threshold, PM Very easy run.
Wednesday - AM Easy bike, PM Easy to moderate run
All that to say just my opinion but its better to keep the quality higher quality and spreading it out a bit more, that might mean spreading the sessions into 10 days instead of a week.
Details with more notes AKA boring
Friday - AM/PM Easy / Recovery
Plan:
AM or PM Easy Bike,
PM/Midday Very Easy run.
Actual: Total days rest
Notes / Why? Because the day at work was massively stressful, any training would not have served me well. Save it for the key session tomorrow.
Saturday - AM Moderate but Hard given the volume
Plan:
AM 25km Moderate Long Run (note not an easy run)
PM Rest
Actual: as per plan, seasons bests for 10 miles to 25km but still at training pace, not racing
Notes / Why? Had recovered well, good nights sleep, followed plan, tomorrow is Sunday easy volume and AM Monday recovery, so can push it a bit
Sunday - AM/PM Easy Volume
Plan:
AM Easy bike 2hr
PM Very Easy Run 6-7km
PM Club Swim
Actual: as plan
Why? Notes: bike felt easy, the run needed to be very easy (finished it feeling better than at the start) Swim, well I can’t really swim well so mainly technical work, not taxing or fatiguing from a fitness point of view. Not much if an addition to the fatigue from yesterday if any, but decent volume
Monday - AM Easy / PM Hard
Plan:
AM 30 minutes easy bike, loosen up the legs.
PM Run 17km with 12km at Marathon pace or a few second per km faster about 85% of optimistic current 5km pace.
Actual: As plan
Why? / Notes: AM bike nice to spin the legs, ended getting of the bike refreshed, lunch time a quick 1.3km at about the 12km main set pace for the PM run. Idea to see if recovered enough for the session. PM session went well, legs heavy in the last 1 - 2km but could have done 13-14km at that pace if really pushing it.
Tuesday - AM Hard / PM recovery/easy
Plan:
AM Bike 60 minutes 2x 20-minute
PM Easy 11km Run
Actual: as plan
Why / Note: Quality in the morning and then appropriate recovery before next key / quality session. Finished the easy run feeling better and the end and better the long it went on.
Wednesday - AM Easy, PM Easy (possibly easy to moderate)
Plan:
AM Bike 90 - 120 minutes easy
PM Run 10-12km easy or easy to moderate with 5x strides
Actual AM 105-minute bike
Notes: sleep good, hydration no so good. Target middle to lower of the ranges planned
That is how I think about planning it 
Have an overall progressive plan and a rough structure so you have a chance of planning it around life and successfully getting the work done, but be prepare to rip it up and change as needed because life and how the body responds.


